Hexa-μ2-chlorido-μ4-oxido-tetrakis[(3-methyl-5-phenyl-1H-pyrazole-κN 2)copper(II)]
نویسنده
چکیده
The title compound, [Cu(4)Cl(6)O(C(10)H(10)N(2))(4)], contains four Cu(II) atoms which are bridged by six chloride anions. The central O atom is located on a crystallographic fourfold roto-inversion axis. Each Cu(II) atom is coordinated by an N atom of a neutral monodentate 3-methyl-5-phenyl-pyrazole ligand, three Cl(-) anions, and one O(2-) anion. The geometry at each Cu(II) atom is distorted trigonal-bipyramidal, with the three Cl(-) ions in the equatorial plane and the N and O atoms in the axial positions.
منابع مشابه
Hexa-μ2-chlorido-μ4-oxido-tetrakis[(morpholine-κN)copper(II)] methanol disolvate
In the title solvate, [Cu4(μ2-Cl)6(μ4-O)(C4H9NO)4]·2CH3OH, each Cu(2+) ion in the tetra-nuclear complex has a trigonal-bipyramidal coordination arising from three bridging chloride ions in equatorial positions and the central μ4-O(2-) ion and morpholine N atom in axial positions. The morpholine rings adopt chair conformations, with the N-Cu bonds in equatorial orientations. In the crystal, the ...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011